The binder-free composite films of reduced graphene oxide （rGO） and activated carbon derived from cotton （aCFC） have been fabricated and used as electrodes for electrochemical capacitors （ECs） to avoid the decre...The binder-free composite films of reduced graphene oxide （rGO） and activated carbon derived from cotton （aCFC） have been fabricated and used as electrodes for electrochemical capacitors （ECs） to avoid the decrease of capacitive performance in traditional process caused by the additional binder. The optimal aCFC is prepared at 850 ℃ when the mass ratio of carbon and potassium hydroxide is 1 to 4. The optimal composite film prepared from the mass ratio of aCFC/GO = 2/1 exhibits porous structure, and has a specific surface area of 849.6 m^2·g^-1 and a total pore volume of 0.61 mL·g^-1. Based on the two-electrode system testing in 6.0 mol/L KOH electrolyte, the optimal composite has specific capacitance of about 202 Fog-1, 374 mF·cm^-2 and 116 F·cm^-3 in terms of mass, area and volume, and shows excellent rate capability and good cyclic stability （91.7% retention of the initial capacitance after 5000 cycles）. Furthermore, the assembled solid-state ECs by using KOH/polyvinyl alcohol as electrolyte show good mechanical stability and capacitive performances after repeated bending cycles. It is proved that this method is effective to fabricate binder-free electrodes for ECs and will open up a novel route for the reuse of waste cotton.展开更多
基金Supporting information for this article is available on the WWW under http：//dx.doi.org/10.1002/cjoc.201700398 or from the author.Acknowledgement This work was supported by the National Natural Science Foundation of China （Nos. U1510121, 21574076, 21501113, 61504076 and 21407100） and Shanxi Province （No. 2015021129）, the Program for the Top Young and Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi （No. 020352901014）, and Graduate Student Education Innovation Project in Shanxi Province （No. 2016BY009）.
文摘The binder-free composite films of reduced graphene oxide （rGO） and activated carbon derived from cotton （aCFC） have been fabricated and used as electrodes for electrochemical capacitors （ECs） to avoid the decrease of capacitive performance in traditional process caused by the additional binder. The optimal aCFC is prepared at 850 ℃ when the mass ratio of carbon and potassium hydroxide is 1 to 4. The optimal composite film prepared from the mass ratio of aCFC/GO = 2/1 exhibits porous structure, and has a specific surface area of 849.6 m^2·g^-1 and a total pore volume of 0.61 mL·g^-1. Based on the two-electrode system testing in 6.0 mol/L KOH electrolyte, the optimal composite has specific capacitance of about 202 Fog-1, 374 mF·cm^-2 and 116 F·cm^-3 in terms of mass, area and volume, and shows excellent rate capability and good cyclic stability （91.7% retention of the initial capacitance after 5000 cycles）. Furthermore, the assembled solid-state ECs by using KOH/polyvinyl alcohol as electrolyte show good mechanical stability and capacitive performances after repeated bending cycles. It is proved that this method is effective to fabricate binder-free electrodes for ECs and will open up a novel route for the reuse of waste cotton.
