A Frank-Read Source Model

The temporal dynamics of the edge dislocation (ED) was studied in this work using the inhomogeneous dissipative sine-Gordon (SG) equation. The consideration was carried out for the force action levels both less and more critical. By SG equation numerical calculations it is shown that at the external force value below a critical one the ED takes a shape close to a semicircle. This shape was used as an initial condition for describing the ED temporal dynamics in the FR source operating mode. A particular solution of the SG equation is proposed that describes the temporal dynamics of half the ED in the FR mode, which rests on a stopper at the origin. It is shown that the proposed particular solution corresponds to the left Archimedes spiral displaced at π/2 counterclockwise relative to the azimuth angle equal to zero. It is noted that the temporal dynamics of the second half of the ED segment rested on the second stopper is described by the proposed particular solution, when it is mirrored relative to the problem symmetry axis and the center of the spiral is displaced to a point with a zero azimuthal angle and a radius equal to the distance between the stoppers. The axis of symmetry is a straight line that is perpendicular and halves the distance between the stoppers. A graphical description of the ED temporal dynamics was plotted in the Cartesian coordinate system based on the proposed particular solution and its mirror and displaced image. It is shown that the particular solution of the SG equation in the RF source operation mode involves two Archimedes spirals symmetrical relative to the problem symmetry axis with equal radii increasing linearly with time, which rotate: one (the spiral center coincides with the stopper at the origin) counterclockwise, the second (the spiral center coincides with the second stopper) clockwise.

Microstructure and Microwave Absorption Properties of Y-Substituted Ni-Zn Ferrites

The Yttrium ions substituted Ni-Zn ferrites powders were prepared using a sol-gel technique. The crystal structure, magnetic properties and microwave absorption properties of the Ni-Zn ferrites powders were studied by X-ray diffraction, vibrating sample magnetometer and vector network analyzer. The results show that the microwave absorption properties of the Ni-Zn ferrites can be improved effectively with the substitution of Y ions. The minimum reflection loss of the Yttrium ions substituted Ni-Zn powder reaches –34.8 dB, with the –20 dB bandwidth over 2 GHz. The Yttrium substitution can improve microwave absorption properties of Ni-Zn ferrite due to smaller grain dimension and the higher specific

Assessment of Heavy Metals Immobilization in Artificially Contaminated Soils Using Some Local Amendments

Three alluvial soil samples with different textures were artificially polluted with chloride solutions of Cd, Pb, Co and chromate solution for Cr. The aqua-regia extracted concentration ranges in the artificially polluted soils were 1134 - 1489 mg·kg-1 for Pb, 854 - 938 mg·kg-1 for Cr, 166 - 346 mg·kg-1 for Co and 44 - 54 mg·kg-1 for Cd. The aqua-regia extracted metals were the highest in the spiked clay soil due to its high adsorption capacity. Rock phosphate (PR), lime-stone (LS) and Portland-cement (Cem) were mixed with the spiked soils at 1% and 2% rates (w/w) and incubated at 30 C for 2, 7, 14, 30, 60, 150 and 360 days. The extracted DTPA metals significantly decreased with different magnitudes with increasing the incubation period accompanied by increases in both pH and EC. The data showed that cement (Cem) treatment dropped the DTPA-Pb from @ 1000 to @ 400 mg·kg-1 in all the studied soils (60% decrease) in the first 2 months while it gradually decreased from 400 to 200 mg·kg-1 (20% decrease) in the next 10 months. Limestone (LS) and rock phosphate (PR) materials were relatively less effective in lowering DTPA-Pb after 12 months of incubation. The data showed also that cement (Cem) treatment was the most effective one in lowering DTPA-Cd by @ 60% as compared to the un-amended soils after 12 months of soil incubation. Extractable DTPA-Co and Cr showed consistent decreases with time down to nearly 50% of un-amended soils due to the effect of the added amendments after 12 months of incubation with superior reductions for the cement treatment in all the investigated soils. The statistical analysis confirmed that in all the studied metals and treatment, cement treatment (Cem) was significantly the most effective in lowering the DTPA extracted metals as indicated from LSD test. It was found that up to 73% and 57% of the applied Pb and Cd, respectively, were fixed by only 1% cement. However, the present study showed that from the practical and economic points of view, that 1% Cement was the best treatment to immobilize Pb and Cd from all the artificially polluted soils.

Zirconium Modified Aluminide Coatings Obtained by the CVD and PVD Methods

The paper presents the comparison of the structures of the zirconium modified aluminide coatings deposited on pure nickel by the CVD and PVD methods. In the CVD process, zirconium was deposited from the ZrCl3 gas phase at the 1000°C. Zirconium thin layer (1 or 7 μm thick) and aluminum thin layer (1.0, 0.7 or 0.5 μm thick) were deposited by the EB-PVD method. Deposition velocity was about 1 ?m/min. The layers obtained by the Electron Beam Evaporation method were subjected to diffusion treatment for 2 h in the argon atmosphere. The obtained coatings were examined by the use of an optical microscope (microstructure and coating thickness) a scanning electron microscope (chemical composition on the cross-section of the modified aluminide coating) and XRD phase analysis. Microstructures and phase compositions of coatings obtained by different methods differ significantly. NiAl(Zr), Ni3Al and Ni(Al) phases were found in the CVD aluminide coatings, whereas Ni5Zr, Ni7Zr2 and γNi(Al,Zr) were observed in coatings obtained by the PVD method. The results indicate that the microstructure of the coating is strongly influenced by the method of manufacturing.

Nanoparticles of In2O3/SnO2 (90/10) and (80/20) at Two Different Proportions and Its Properties

ITO nanoparticles were obtained by combustion reaction of urea as fuel. The gel form structures were fired at 350°C in furnace for 20 min to yield powdery products and these products were calcined to five different temperatures from 100°C to 500°C for an hour to yield ITO powders. From the scanning electron microscopy (SEM) photographs and particle size analysis the average sizes of the cubic particle of powders are found to be less than 15 nm and less than 20 nm respectively. The ratio of doping concentration In/Sn is 90/10 and 80/20. The X-ray diffraction (XRD) data were evaluated by Scherer equation for the estimation of the average crystal size of the powders (less than 20 nm) for 90/10 and (less than 25 nm) for 80/20. The synthesized ITO powder characterized by XRD, UV-Vis-NIR and PL shows high specific surface area and possesses small primary crystallite size and good optical band gap.

Experimental Investigation of Bed Joint Reinforcement Corrosion in Masonry Mortars

The paper investigates the behaviour against corrosion offered by seven masonry mortar compositions to the reinforcement placed in masonry bed joints. Durability protection was evaluated on the basis of four criteria: carbonation area of the specimens, mass loss of steel, electrochemical potential and presence of chloride ions. Tests were performed against two corrosive environments, with and without chloride ions, and were carried out for three periods: three, six and thirty three months. Two types of steel were used, plain steel and galvanized steel. Moreover, the steel protective action of a corrosion inhibitor, sodium nitrite, was examined. A qualitative comparison approach against prototype concrete-like mortars was used. The results showed that the selected masonry mortars did not exhibit similar properties against corrosion to those of concrete and that the addition of sodium nitrite decrease of the corrosion rate only 5% - 20% did not meaningfully improve durability properties. Nevertheless, the addition of lime in small quantities did not have a negative impact on the mortars’ durability characteristics, e.g. the same average corrosion rate.

Influence of Plastic Deformation and Aging Process on Microstructure and Tensile Properties of Cast Ti-6Al-2Sn-2Zr-2Mo-1.5Cr-2Nb-0.1Si Alloy

In the present work, titanium alloy with a composition of Ti-6.5Al-3Mo-1.9Nb-2.2Sn-2.2Zr-1.5Cr (TC21) was subjected to plastic deformation and aging processes. A Plastic deformation at room temperature with 2%, 3% and 4% stroke strain was applied on the studied samples. Then, the samples aged at 575°C for 4 hr. By applying different plastic deformation ratios, the structure revealed an elongated and thin β-phase embedded in an α-phase. Secondary α-platelets were precipitated in the residual β-phase. Maximum hardness (HV440) was obtained for 4% deformed + aged samples. Minimum hardness (HV320) was recorded for the as-cast samples without deformation. The highest ultimate tensile strength of 1311 MPa was obtained for 4% deformed + aged samples due to presence of high amount of dislocation density as well as precipitation of secondary α-platelets in the residual β-phase. The lowest ultimate tensile strength of 1020 MPa was reported for as-cast samples. Maximum elongation of 14% was registered for 4% deformed + aged samples and minimum one of 3% was obtained for as-cast samples. Hence, strain hardening + aging can enhance considerably the elongation of TC21 Ti-alloy up to 366% and 133% in case of applying 4% deformation + aged compared to as-cast and aged samples without applying plastic deformation, respectively.

Zinc and Chromium Load in Road Dust, Suspended Particulate Matter and Foliar Dust Deposits of Anand City, Gujarat

Anand, the milk capital of India, is a developing city with increasing vehicles and developmental activities going on at a fast pace. This study attempts to investigate the zinc and chromium concentration in street dust, suspended particulate matter and in foliar dust deposits. Ten sampling locations were selected based on the traffic density on the roads and different anthropogenic activity. Sampling was carried out in the dry months of January to March 2011. The range of Zn and Cr was 16.82 - 108.29 ppm and 118 - 151.5 ppm in the street dust respectively. Zn concentration in Suspended particulate matter lies in the range of 12.41 to 86 ppm and Cr concentration between 75 to 130 ppm. The range of Cr in foliar deposited dust varied from 79.54 ppm to 31 ppm. Whereas, for Zn maximum concentration was in S10 which is 42.34 ppm and minimum was in site S9, 23.73 ppm. ANOVA single factor showed that at 0.05 level of significance site wise variation of zinc and chromium concentration in SPM, Street dust and foliar deposited dust was not significant signifying similar source of contamination. Which is further strengthened by the good positive correlation found between the Zn and Cr concentration of street dust, leaf deposited dust and SPM. The Contamination Factor in the sites where metal concentration was high was 1.24 in S10 and 1.06 in S5 for Zn. For chromium the value of CF was 1.77 in S10 and 1.67 in S5. These values indicate that street dust is moderately contaminated with respect to zinc and chromium.

A Novel Technique for Determination of Flow Characteristics of Blast Furnace Slag

A study of flow characteristics of blast furnace slag helps determine its softening and flow (liquid-mobility) temperatures. The slag with a narrow difference between the two temperatures is termed a “Short Slag”. Its formation ensures higher rates of slag-metal reactions with the trickle of the slag soon after its formation exposing fresh mass for faster reactions, the trickling slag, creating fresh interfaces facilitating slag-metal exchanges. In the present work, a novel technique is adopted to determine the flow characteristics of blast furnace slag obtained from different industrial blast furnaces. It is seen that the results so obtained agree very closely with the values obtained from adopting conventional methods of determining the liquidus temperature using “slag atlas”. It is observed that under the range of compositions studied a high C/S ratio combined with a high MgO content in the slag is beneficial to the B.F. process as it renders a “short slag”.

Sensitivity of Nanostructured Iron Metal on Ultrasonic Properties

The present investigation is focused on the influence of the nanocrystalline structure of pure iron metal on the ultrasonic properties in the temperature range 100 - 300 K. The ultrasonic attenuation due to phonon- phonon interaction and thermoelastic relaxation phenomena has been evaluated for longitudinal and shear waves along , and crystallographic directions. The second-and third-order elastic constants, ultrasonic velocities, thermal relaxation, anisotropy and acoustic coupling constants were also com- puted for the evaluation of ultrasonic attenuation in this temperature scale. The direction is most ap- propriate to study longitudinal sound waves, while , direction are best to propagate shear waves due to lowest values of attenuation in these directions. Other physical properties correlated with obtained results have been discussed.

Analysis of the Behavior of Local Cooking Utensils in Tap Water, Salt Tap Water and Vegetable Oil According to the Temperature

In Senegal the aluminum scrap are mainly recycled kitchen utensils [1]. The craftsmanship poses the problem of the quality of finished products [1] especially when we know they are used for everyday cooking. Given that none of these alloys should not be used to make cooking utensils if we refer to the EN 601 standard in July 2004, which refers to this regard [1], this study aims at analyzing behavior of these alloys reconstructed in three settings (tap water, vegetable oil and salt water more than 3 grams per liter), chosen for their importance in Senegalese cuisine. Significant loss of mate- rial was observed mainly by intergranular corrosion. It would be interesting that additional studies be conducted to ex- amine the impact of the daily use of these alloys on the health of Senegalese.

Investigation on Microstructure and Grain Refining Performance of a New Type of Al-3Ti-1C Master Alloy

Grain refining process plays a significant role in preventing columnar and coarse grains and it encourages fine grain formation. Although Al-Ti-B master alloys use widely as aluminium grain refiners, there are several problems in their applications. So, this kind of master alloys use less than last. Because of great properties of Al-Ti-C refiners, they can be considered as suitable candidates for use instead of Al-Ti-B master alloys. In recent years, Al-Ti-C refiners have attracted huge attention among researchers. In this paper, Al-3Ti-1C master alloy is prepared with a melting reaction method. This method involves adding graphite powder and fine titanium particles into superheated pure aluminium. Then microstructure of this master alloy is studied by scanning electron microscope (SEM) and its phases are distinguished by energy dispersive spectroscopy (EDS). In the next part, 200 ppm of Al-3Ti-1C master alloy is added to pure aluminium and its refining efficiency is compared with the condition in which TiC powders are added to aluminium melt directly. It is found that the fading time for both Al-3Ti-1C and TiC powder is about 15 minutes and in overall, grain refining efficiency of Al-3Ti-1C is more than TiC powders in 60 minutes.

Technological Basics for Production of Low-Temperature Superconductors

The technological principles of low-temperature superconductor production for the magnetic system of the International Thermonuclear Experimental Reactor (ITER) that provides continuity of a superconductor billet in the superconductor production are considered.

Deformation Nano-Mechanisms Occurring on the Interface of Dissimilar Materials Joined in Solid Phase by Means of High Temperature Rolling

Nano-mechanisms of crystal lattice deformation on the interface of dissimilar materials (Cu-Nb), joined by vacuum rolling in solid phase under high temperature (950℃) were studied by means of high resolution electron microscopy. Input of carriers of rotation modes—nano-dipoles of partial disclinations and nano-twist disclinations in the form of double spirals in deformation mechanisms were analyzed. The role of these mechanisms in decrease of shear stability of the interface areas and in production of high-quality rolled metal is discussed.

Synthesis of Solid Acid Catalysts Based on TiO₂- SO₄^2-and Pt/TiO₂- SO₄^2-Applied in <i>n</i>-Hexane Isomerization

The physicochemical properties and catalytic activity of pure and sulfated titanium oxide (TiO2 and ) is described in this work. Titanium hydroxide synthesized by the sol-gel method was impregnated with a 1 N H2SO4 solution, varying amount of sulfate ions () in the range from 10 to 20 wt%. Pure and modified hydroxides were calcined at 500°C for 3 h and then characterized by TGA-DTG, XRD, BET, FT-IR, potentiometric titration with n-butylamine and 2-propanol dehydration. Catalytic activity of materials was tested in the n-hexane isomerization at 350°C. The results showed that TiO2 and mainly developed anatase phase. All have acceptable specific surface area (95-105 m2/g). Potentiometric titration with n-butylamine revealed that showed higher acidity (430-530 mV) than compared to pure TiO2 (﹣15 mV), indicating that this oxide only has weak acidity. The results showed good relationship between acidity determined by potentiometric titration with n-butylamine and the catalytic activity evaluated by 2-propanol dehydration and n-hexane isomerization. Titanium oxide with 20 wt% ofions was the material that demonstrated the highest catalytic activity for both reactions.

The Comparative Study of the Temperature Distribution of Fiber Laser with Different Pump Schemes

Based on the structure of the long fiber laser (YDCFLs) with different pump schemes using high pump power, the nonlinear coupled and heat dissipation equations are solved numerically. Using the finite-difference method, we have determined the temperature distribution along the radial and axial directions of the fiber laser (YDCFLs) for the forward pump schemes of 200 W with reflection Rp2, backward pump schemes of 200 W with reflection Rp1 and for bidirectional pump scheme of 100 W each side. The results are: the temperature distribution for bidirectional pump mode is more even than that for forward pump with reflection Rp2 and than that for backward pump with reflection Rp1. The results show that the maximum temperature difference between different schemes is 57.51°C, and when the air-clad width decreases, the temperature in the core regions also decreases and does not affect to the cladding radius regions. We summarize that the temperature in the core and in cladding radius regions decreases when the outer radius cladding increases.

Heavy Metal Contaminated Food Crops Irrigated with Wastewater in Peri Urban Areas, Zambia

Studies on peri urban farming in Zambia have not adequately tackled the issues pertaining to heavy metal contaminated wastewater irrigation farming. The study investigated heavy metal contamination of water, soils and crops at two peri urban areas in Zambia. Two study sites were New Farm Extension in Mufulira Town in the Copperbelt Province and Chilumba Gardens in Kafue Town in Lusaka Province. The heavy metals investigated were lead, copper, cobalt, nickel and chromium. These heavy metals were found to be higher than acceptable limits in wastewater used to irrigate crops and there are potential human health risks associated with consumption of heavy metal contaminated food crops which have implications on the livelihoods of people. Samples of water, soil and crops were collected and analysed for lead (Pb), copper (Cu), chromium (Cr), cobalt (Co) and nickel (Ni) using the Atomic Absorption Spectrometer (AAS). The data on heavy metals was analysed using mean, standard error and T-test. The results indicated that the levels of heavy metals in wastewater, soil and food crops were above acceptable limits at two study sites. It can be concluded that there was heavy metal contamination of wastewater, soil and food crops at the two peri-urban areas in Zambia. The study highlighted the actual levels of heavy metal contaminant uptake in food crops consumed by the peri urban population. The information from this study can be used by the relevant authorities to develop appropriate measures for monitoring and control of heavy metal contamination in wastewater irrigation farming systems in peri urban areas inZambia.

Comparative Study of Corrosion Inhibition Efficiency of Naturally Occurring Ecofriendly Varieties of Holy Basil (Tulsi) for Tin in HNO₃Solution

Weight loss technique has been used to study the corrosion inhibition efficiency of tin in HNO3 solution by using the leaves and stem extract of different varieties of Holy Basil viz. ocimum basilicum (EB),, ocimum cannum (EC) and ocimum sanctum (ES). The results show that all the varieties under study are good corrosion inhibitors, among which leaves extract of EB is the most effective. Corrosion inhibition efficiency increases with increasing concentration of inhibitor and it also increases with increasing concentration of HNO3 solution. Inhibition efficiency was found maximum up to 96.19% for tin in with 0.6% leaves extract.

Adhesion Studies of Diamond-Like Carbon Films Deposited on Ti6Al4V Alloy after Carbonitriding

Diamond-like Carbon (DLC) coatings have attracted significant attention due to their low friction coefficient, high degree of hardness, chemical inertness, and high wear resistance as well as and their many possible uses in metallurgical, aeronautical, and biomedical applications. However, DLC has low adhesion strength to metallic substrates. Carbonitriding was performed before DLC deposition to improve this adherence. Different concentration of nitrogen in the gas mixture was used during the carbonitriding of Ti6Al4V alloy. DLC films were subsequently grown from methane using plasma enhanced chemical vapor deposition. The samples were characterized with Raman scattering spectroscopy, nanoindentation, and tribological tests. Films from 80.0% N2 had the best friction coefficient (0.07) and a critical load of ~22 N. In the scratching test, these films had adhesive failure and they completely detached from the substrate only in the end of the tests. SEM images show carbonitring promoted a significant increase in the surface defects (homogeneously distributed) but without the presence of microcracks. EDX analysis indicated that nitrogen element was diffused throughout the thickness of the samples. Hydrogen and carbon atoms from carbonitriding formed a diffusion-barrier layer that can be used as the first step for DLC deposition. This carbonitriding can also provide a carbide layer, which serves as the precursor for the nucleation and growth of DLC films.

Modelling of Al-Cu-Mg-Fe-Ni Aluminium Alloy

Hot deformation characteristics of Al-Cu-Mg-Fe-Ni aluminium alloy have been studied in the temperature range 350°C - 450°C and strain rate range 0.001 - 0.4 s-1 using hot compression tests. The experimental results were used to develop a model for predicting the material characteristics during hot deformation. A series of plane-strain compression (PSC) tests were carried out at 950°C and a strain rate of 0.1, 1 and 10 s-1 to several strain levels.